Description
This WorkPackage aims to
develop laser processes
to assist active cuff-on wafer fabrication. Precisely, this WP consists
of there
tasks: the first task is to develop a laser process to drill holes in
silicone
so that the platinum pods contact the nerve; the second task is to
explore
electrode contact surface treatments, such as iridium oxide coating;
the third
task is using different techniques to characterise the surface of the
silicone
sheets before and after metallization.
Achievement
Concerning the
first
task and as shown on Figure 1, holes can be drilled by laser in
silicone rubber
(PDMS) until the excimer laser beam touch Pt without removing it.
For the second task,
coating electrodes of platinum with iridium oxide may lead to lower
impedance.
This coating is still unsuccessful but it has been shown in some
scientific
meetings (for example The Eye and The Chip 2006, World Congress on
Artificial
Vision held in Detroit in June 15-17, contribution of Stuart Cogan),
that
iridium oxide coating can yield very different results depending on the
deposition method and that erosion might still be a limiting factor in
chronic
implants. At this time however, the prospect of incorporation of
iridium oxide
coating in the final design seems rather dim.
For the
third task,
the structure and morphology of untreated and treated (i.e. laser
irradiated)
silicone rubber (before metallization) have been characterized using
optical
microscopes, Scanning Electron Microscope (SEM), Analytical
Transmission
Electron Microscope (ATEM) and Raman spectroscopes.
SEM shows that
morphology of irradiated PDMS (Figure 2) is completely different than
the one’s
of non-irradiated PDMS. The roughness is increased and is favourable to
nerve
contacts once metallized.
Characterization of
silicone rubber after metallization using SEM shows that Pt metallized
tracks
are constituted of Pt balls (Figure 3) and that there is a strong
correlation
between the measured DC resistance of the tracks and the size of the Pt
balls;
which depends on the irradiation conditions.
![WP23](WP23.JPG)
When Pt balls are
bigger, there are observed to be in better contact with each other so
that electrical
conductivity is higher thus leading to a smaller DC resistance.
We
performed traction tests on Pt tracks. We determined DC
resistances as a
function of the track elongation and we observed that DC resistances
become
infinite when elongation is about 2 %. However, when tracks are
relaxed, DC
resistances are again finite and are slightly higher than before
elongation. We
observed that tracks mechanical rupture occurs when elongation is
superior to
53 % (after relaxation DC resistances remain infinite).
In
addition to adhesion and traction tests, we
performed a test at room temperature in a saline solution to know the
evolution
of DC resistance with time and maybe erosion or dissolution of Pt in
saline
solution. For this experiment, we welded with tin 2 tin plated copper
wires on 2
Pt contacts and we immersed
the track in a saline solution (see Figure 4).
![WP24](WP24.JPG)
DC resistance is initially equal to 15 Ohms.
It decreases for few days and then increases
for 3
months up to 30 Ohms before decreasing for 3 months up to its initial
value. This
result shows that saline solution does not damage our Pt tracks.
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