Aims

Introduction to the chemical thermodynamics of phase equilibriums in solutions of non-electrolytes.

Main themes

- Thermodynamical properties of gases and their mixtures: the corresponding state principle,the virial state equation and the cubic state equations (Redlich-Kwong-Soave and Peng-Robinson),the mixing rules,
- The fugacities of gases and liquids and the Clapeyron equation,
- The thermodynamic properties of mixtures: partial molar properties changes of mixing, the ideal solution, the excess thermodynamic functions,
- The chemical potential and the activity and relationship with fugacity, the Gibbs-Duhem equation
- Models of the liquid phase: Scatchard-Hildebrand,FlorHuggins,Van Laar, Wilson, NRTL, UNIQUAC and UNIFAC
- Study of the equilibriums between vapour and liquid at low and high pressure, liquid-liquid equilibriums and solid-liquid equilibriums

Other credits in programs