Demoustier Sophie; Jonas Alain coordinator; Van Ruymbeke Evelyne;
Two main themes will be discussed :
The first theme deals with the physics of polymer materials, and presents the main properties of these materials while establishing in a formal way the relationship with the physical characteristics of the chains at the molecular scale.
The second theme is an introduction to the chemistry of these materials, which presents the main classes of polymerization reactions, and relates the resulting molecular structure and the properties of the materials.
The contribution of this Teaching Unit to the development and
command of the skills and learning outcomes of the programme(s) can be
accessed at the end of this sheet, in the section entitled
“Programmes/courses offering this Teaching Unit”.
At the end of this learning unit, the student is able to :
Contribution of the course to the program objectives
With respect to the program of the Master in Chemical and Materials Science Engineering, this course contributes to the development and the acquisition of the following learning outcomes:
LO 1.1.Identify and use concepts, laws, and reasoning related to a problem of limited complexity.
LO 1.2. Identify and use modelling and computational tools to solve this problem.
Specific learning outcomes of the course
At the end of this course, students will be able to :
Determine the parameters required to model a macromolecular chain by a freely-jointed chain model, a wormlike model, or a model of rotational isomeric states; explain using statistical physics how these parameters vary with molar mass, temperature or chemical nature of the repeat unit;
Use statistical physics and a freely-jointed chain model to compute the retraction force resulting from increasing the distance between the chain ends of a polymer chain; explain the main characteristics of this force; derive the stress/strain curve of a rubber band, starting from equations describing the statistical behavior of its chain segments, and from the environmental constraints of the experiment;
Describe phenomenologically the glass transition of polymers and the relaxation phenomena associated with it, on the basis of the notion of free volume. Use this approach to explain how the glass transition is sensitive to the temperature and the rate of measurement;
Describe the morphology of a semicrystalline polymer at different scales, and draw a scheme of this morphology; state how this morphology controls the properties of the material; enumerate the parameters which control the melting temperature of a polymer; derive the equation relating this melting temperature and the lamellar thickness; list the main experimental facts that must be included in any theory of polymer crystallization, and present briefly some kinetic theories able to explain these facts;
Derive the principle of time/temperature equivalence for the elastic modulus of polymers, and describe its practical consequences for the use of such materials; quantify these effects by the Williams-Landel-Ferry equation;
Define and explain different concepts related to the molecular structure of polymers (topology, repeating units linking, configurational structures, average molecular weights and dispersity) ;
Describe and explain the mechanisms of the main methods of polymer synthesis : chain-reaction polymerizations (free radical polymerization, controlled radical polymerizations, coordinative polymerization and ionic polymerizations) and step-reaction polymerization; list and give the impact of the main parameters that govern the kinetics for each polymerization method ; establish relations between the polymerization method and the resulting molecular characteristics (architecture of the chain, regioselectivity, tacticity, molecular weight distribution, ¿) of the polymer chains;
Describe the structure of the main types of copolymers (random, alternating, graft and block copolymers) and discuss about the synthesis method and conditions in which each type of copolymer can be obtained; predict and justify the global composition of random copolymers based on the reactivity ratios of a given couple of monomers ;
Select and describe an appropriated polymerization method of a given monomer in order to obtain a polymer with specific molecular characteristics ;
Describe different polymerization processes (bulk polymerization, polymerization in solution, in suspension, in emulsion and interfacial polymerization) and state the advantages and drawbacks of each process.
1. Physics part :
1.1. Main characteristics of macromolecular chains
1.2. Elasticity of macromolecules, and elasticity of elastomer materials
1.3. The glassy state and the glass transition of polymer materials
1.4. Viscoelasticity and rheology of polymers
1.5. Semicrystalline polymers and polymer crystallization
2. Chemistry part :
2.1. Step polymerization
2.2. Free radical polymerization
2.3. Coordinative polymerization
2.5. Ionic polymerization
2.6. Controlled radical polymerization
The course mixes formal presentations by the teachers with exercises done by the students. These exercises serve either to raise questions, or to solve issues. Parts of the course will be in flipped classroom format. The visit of a production plant may be included in the course.
Written exam at the end of the course, comprising small exercises and questions on the main concepts of the course. An oral exam may also be organized; this will be mentioned at the beginning of the course by the teachers. For the part of the course taught in flipped classroom format, an optional continuous evaluation is proposed to students.
This course requires to have a knowledge of thermodynamics, statistical physics and organic chemistry.
L'ouvrage de référence suivant est recommandé / the following textbook is a good reference:
Paul C. Hiemenz & Timothy P. Lodge, Polymer Chemistry, 2nd edition, CRC Press:Boca Raton, 2007.