Polymer chemistry and physical chemistry (part 1 : Polymer chemistry)

lchm2261a  2017-2018  Louvain-la-Neuve

Polymer chemistry and physical chemistry (part 1 : Polymer chemistry)
3 credits
22.5 h + 7.5 h
Q1
Teacher(s)
Gohy Jean-François; Jonas Alain;
Language
English
Prerequisites
LCHM1361 or any other equivalent course
Main themes
After recalling the basics of chain polymerization methods, the different synthetic strategies existing today will be
studied (anionic, cationic, standard radical, controlled radical and coordinative polymerization methods). The scope and limitations
of each method will be systematically discussed. Mechanistic and kinetic features will be then studied for each polymerization
method. Special emphasis will be finally put on the control of macromolecular architectures.
 The course is in flipped classroom, project-based format.

All these topics will not be necessarily covered each year.
Aims

At the end of this learning unit, the student is able to :

1

This course aims at providing a deep understanding of chain polymerization methods.

At this end of the course, the students are expected to deeply understand and explain the following items:

- The state of the art in chain polymerization methods.
- The concepts of controlled and living polymerizations as well as their impact on the polymer characteristic features (molar mass,
dispersity index, architecture)

- The technological issues related to chain polymerization.
- Furthermore, the students will be able to use the above mentioned concepts to propose relevant synthetic methodologies for case
studies.

The contribution of this Teaching Unit to the development and command of the skills and learning outcomes of the programme(s)
can be accessed at the end of this sheet, in the section entitled ¿Programmes/courses offering this Teaching Unit¿.

 

The contribution of this Teaching Unit to the development and command of the skills and learning outcomes of the programme(s) can be accessed at the end of this sheet, in the section entitled “Programmes/courses offering this Teaching Unit”.
Content
  1. Introduction: Living and controlled chain polymerizations
  2. Atom-transfer radical polymerizations (ATRP)
  3. Nitroxide-madiated radical polymerizations (NMP)
  4. Reversible addition-fragmentation chain-transfer polymerization (RAFT)
  5. Anionic polymerizations
  6. Living ring-opening polymerizations (LROP)
  7. Organocatalytic ring-opening polymerizations
  8. Control of macromolecular architectures
  9. Mechanistic transformations
  10. Supramolecular polymerizations
Other information
Documents: Written notes and reference books will be made available for the students.
Faculty or entity
CHIM


Programmes / formations proposant cette unité d'enseignement (UE)

Title of the programme
Sigle
Credits
Prerequisites
Aims
Master [120] in Chemistry